Yes, provided you have two controllers and a game with two-player or coop play ability.
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If you buy the PlayStation or third party multi-tap you can play with 4 players on a playstation 2.
You cannot play Playstation 4 games on a Playstation 4 console. You are also unable to play Playstation 3 games on the Playstation 4.
No, the Playstation 4 is not backwards compatible and you can only play Playstation 4 games on it.
The Call of Duty 4 campaign is strictly single player.
No, only old PS3 Game consoles with 4 USB ports can play some PS2 game titles.