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No trainer has zangoose in emerald.
You can't get it in emerald.
You have to get it in a trade.
Zangoose is only found in Pokemon Ruby, which means you have to trade it from Ruby or from someone who has one.
Zangoose, the rival of Seviper, is in Emerald, Ruby, and Saphire. Zangoose is also in Mystery Dungeon Red Rescue Team and Blue Rescue Team.