You can't get it in emerald.
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Zangoose is only found in Pokemon Ruby, which means you have to trade it from Ruby or from someone who has one.
Trade it from pokemon ruby
No trainer has zangoose in emerald.
I hardly think you can catch a Zangoose in Pokemon FireRed. Only thing you can do is to trade it from Emerald, Ruby, or Sapphire. Answered by: QWERTY
Zangoose, the rival of Seviper, is in Emerald, Ruby, and Saphire. Zangoose is also in Mystery Dungeon Red Rescue Team and Blue Rescue Team.