Zangoose, the rival of Seviper, is in Emerald, Ruby, and Saphire. Zangoose is also in Mystery Dungeon Red Rescue Team and Blue Rescue Team.
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The way you can get zangoose in Pokemon heartgold is in the safari zone.
Zangoose does not appear in Pokemon sapphire, but you CAN get it. To get it, you must trade Pokemon with your friend if your friend has Pokemon ruby which is the only game you can get zangoose in. Or you can just buy Pokemon ruby.
Pokemon that have claws, horns etc. Although Zangoose cannot learn the TM cut.
You have to get it in a trade.
Zangoose is only found in Pokemon Ruby, which means you have to trade it from Ruby or from someone who has one.