Darumaka learn fire punch at level 22
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Fire Punch is not an TM or HM in Pokemon FireRed. It is learned by level up or by breeding for Pokemon that can learn it.
No, Flareon cannot learn Fire Punch
He learns it at level 25 as soon as he evolves from Gastly.
You can only "learn" Fire Punch in Diamond via breeding a Pokemon with another who already knows Fire Punch (Magmar for example)