No.
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Metagross cannot learn Thunderbolt. Metagross can learn only two Electric-type moves; Magnet Rise and Thunder Punch. Magnet Rise can be taught by using a Move Reminder NPC. Thunder Punch can be taught by using a Move Tutor NPC in the various Pokemon games where they are available.
No, Flareon cannot learn Fire Punch
Darumaka learn fire punch at level 22Hope I helped
You can only "learn" Fire Punch in Diamond via breeding a Pokemon with another who already knows Fire Punch (Magmar for example)
IN GOLD VERSIONNo, it can't but, you can go to celadon mart and buy it to him. Cyndiquill and Quilava can't learn fire punch, but Typhlosion can.