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Darumaka learn fire punch at level 22Hope I helped
Fire Punch is not an TM or HM in Pokemon FireRed. It is learned by level up or by breeding for Pokemon that can learn it.
No, Flareon cannot learn Fire Punch
Go to the Move Tutor who teaches Poke'mon moves in exchange for items called Heart Scales. You can find him in the town North of Meteor Falls. When you give him a Heart Scale, he will ask you which Pokemon wants to learn a new move. Choose your Blaziken. Then he will give you a list of moves. Choose Fire Punch.
He learns it at level 25 as soon as he evolves from Gastly.