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Go to the Move Tutor who teaches Poke'mon moves in exchange for items called Heart Scales. You can find him in the town North of Meteor Falls. When you give him a Heart Scale, he will ask you which Pokemon wants to learn a new move. Choose your Blaziken. Then he will give you a list of moves. Choose Fire Punch.

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Q: In Pokemon Emerald how do you teach Blaziken Fire Punch?
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