Go to the Move Tutor who teaches Poke'mon moves in exchange for items called Heart Scales. You can find him in the town North of Meteor Falls. When you give him a Heart Scale, he will ask you which Pokemon wants to learn a new move. Choose your Blaziken. Then he will give you a list of moves. Choose Fire Punch.
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Sorry. Blaziken is the only Fire type starter that does not learn Blast Burn
You can only teach it in Emerald with a move tutor sorry :(
level it up and teach it strong moves and try to teach it moves with tms like shadow ball that is good against psychic actually in Pokemon emerald version the Blaziken wont take shadow ball .....soooo...idk wat your playing Lvl 100???
go to lilycove department and buy the TM which includes something to do with fire (it is fire blast). then teach it to blaziken.
In Pokemon emerald there is the Battle Frontier. Perhaps in the far left region of the island you will see a cabin with a red roof and such. Go inside and you would see two old ladies. They are both move tutors and the one on the right can teach your Pokemon fire punch and all other punches. It is worth 48 bp so have enough bp to buy it for your Pokemon.