go to lilycove department and buy the TM which includes something to do with fire (it is fire blast). then teach it to blaziken.
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Sorry. Blaziken is the only Fire type starter that does not learn Blast Burn
fire blast
Go to the Move Tutor who teaches Poke'mon moves in exchange for items called Heart Scales. You can find him in the town North of Meteor Falls. When you give him a Heart Scale, he will ask you which Pokemon wants to learn a new move. Choose your Blaziken. Then he will give you a list of moves. Choose Fire Punch.
well if you want a straight answer you should teach it neither and teach it splash
Blaziken is a Fighting and Fire type pokemon.