well if you want a straight answer you should teach it neither and teach it splash
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D/P 16 Ember 25 Fire Spin 38 Fire Blast 48 Flare Blitz Pt/HG/SS 10 Ember 15 Flame Wheel 24 Fire Spin 37 Fire Blast 46 Flare Blitz
Charizard can't learn flare blitz because its not a move, maybe your talking about Blast burn it needs to be level 50 to learn it then go to two island and go north to a house go in and talk to the lady show her your charizard and she will teach it blast burn.
It doesn't. Flare Blitz is a move only fire-type starter Pokemon can learn.
I'm 99.999999999...% positive that charizard learns flare blitz at level 66.
Close combat, Fire spin, Calm mind, and Flare blitz