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It doesn't. Flare Blitz is a move only fire-type starter Pokemon can learn.
you cant get that move in that game
As far as I know, the move Flare Blitz is not a TM and thus cannot be purchased or found in the field. It is instead learned by select Fire-type Pokemon via a level-up. Two such Pokemon are Infernape and Rapidash.
D/P 16 Ember 25 Fire Spin 38 Fire Blast 48 Flare Blitz Pt/HG/SS 10 Ember 15 Flame Wheel 24 Fire Spin 37 Fire Blast 46 Flare Blitz
Flare Blitz and Close Combat have the same power, but different effects.