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You don't need to have caught any pokemon. All you need is the event or the action replay code to make the event. Then go catch Arceus. You should probably use a master ball or ultra or timer balls.
There is no such code for pokemon platinum
Arceus has no cheat code for Leaf Green, because Leaf Green was released years before Platinum, Pearl and Diamond in which Arceus first appears.
There is no current code yet for rebattling arceus but if you have the Pokemon modifier code just throw away no master balls and you will run into arceus where you can encounter Pokemon
nentendo event sorry but i dont think its out anymore but i have darkrai