The Pokémon that can learn Hypnosis are the following: Poliwag, Poliwhirl, Poliwrath, Politoed, Gastly, Haunter, Gengar, Drowzee, Hypno, Exeggcute, Exeggutor, Hoothoot, Noctowl, Yanma, Stantler, Ralts, Kirlia, Gardevoir, Spinda, Lunatone, Glameow, Purugly, Bronzor, Bronzong, Spiritomb and Darkrai
chingling can lear hypnosis but it has to evole in to chimaco
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Drowzee and Hypno are top choices. but most psychic Pokemon know/can learn Hypnosis.
Munna and Sigilyph.
you can catch a ralts on route 102 and put an everstone on it, then it will learn hypnosis at level 41
Its not a TM. Your Pokemon has to learn it. like Gastly :) (Gengar in lvl 100 with hypnosis is pwnage :p)
Only certain Pokemon can learn it but you can't find the TM