you can catch a ralts on route 102 and put an everstone on it, then it will learn hypnosis at level 41
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I only know 3 moves that makes Pokemon fall asleep. GrassWhistle - Roselia learns it by level up Yawn - Dunsparce learns it by level up Hypnosis - Drowsee knows it when captured in Pokemon Heart gold And Soul silver.
Yes Umbreon learns hypnosis I don't know when though. Get it to level 60 and go to the move toutor.
It learns double egde at level 63. Double edge is that last move Aggron learns.
If you have an Abra, the best hypnosis Pokemon is alakazam. So catch an Abra, evole it to a kadabra, the evolve it to an alakazam to have the best hypnosis Pokemon
Hypnosis is not a TM.