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Fish with the Good Rod you found on the Fishing Guru's brother's house in Fuchsia City. You can find Poliwags in the pond right there behind his house.

This is a list of places where Poliwags will appear as you fish with Good Rod:

Route 6

Safari Zone

Cerulean Cave

Route 22 and 23 (towards Victory Road)

Route 25 (Bill's House)

Fuchsia City

Island 2, 3 and 4

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