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poliwag is usually on the beach.
I'm sorry, but you will have to trade from Pokemon LeafGreen or FireRed. There is no way to find a Poliwag in the wild in Emerald.
Poliwag is not available in Pokémon Emerald Version. You must trade it from Pokémon FireRed or LeafGreen Versions. Over and out...
You'll need to trade for it.
Poliwag is not catchable in Ruby, Saphire or Emerald.