yes u can just be patient..:p
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You can get Poliwag by fishing (using the Super Rod) on the Elite 4 trail.
good rod or super rod next to bills house.You can also catch a Poliwhirl there.Poliwag is not in leafgreen you get horsea instead via the good rod and super rod. To get poliwag trade one from firered.
Yes.
You can not catch a Poliwag with an old rod. The only thing that you can catch with an old rod is a Magikarp. You need at least a good rod to catch a Poliwag. To get the good rod you will need to go to the house near the Warden House in Fuschia City. A fisherman will then give it to you. With it you will travel to Cerulean City and go to Bill's house and fish right by his house, you will then find a Poliwag.
To find a Poliwag in Soul Silver, just use your old rod in the water in the Ruins of Alph. The first time I put my rod in the water, I caught one! :)