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You cannot catch Wailord. You can, however, catch Wailmer, which evolve into Wailord starting at level 40.
It is in Undella Bay, wait for rippling water, then Surf into it. You'll have a 5% chance of finding it in the wild.
wailord is in undella bay
Wailord is the largest Pokemon followed by groudon.
If you breed a female Skitty and a male Wailord then you get a Skitty but if you breed a female Wailord and a male Skitty then you'll get a Wailmer.