Xenarthra - a mammal in South America.
Xoloitzcuintli - a dog.
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There is one called Frangelico. The bottle is brown and looks like a monk in a robe.
Yak
You may be thinking of the East Indian 'Dhole' dog.
A gas that *sounds* like it begins with a "z" is xenon.
The alpaca is a South American animal. It looks like a small llama.