Pokemon Ruby,Sapphire, and Emerald are the games you catch him, But you can get him Via trade in any higher generation games ( Diamond, Pearl, Platnum, Heart Gold Soul Silver,) to be continued later on
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I'm sorry to say that there is no possible way to breed Rayquaza in any Pokemon game on the planet. :(
You can only get Rayquaza in Pokemon Ruby, Sapphire, and Emerald. If you want to get a Rayquaza in Pokemon Leafgreen or Firered, you will have to get a second Game Boy Advance or SP with a link cable to trade Rayquaza into your firered or leafgreen.
You can't get Rayquaza on Pokemon Pearl. You have to MIGRATE it
Rayquaza is in the movie Pokemon: Destiny Deoxys
Pokemon ruby, sapphire, and emerald. The legendaries are groudon kyogre and rayquaza.