u cant it not tm :(
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Headbutt dosn't come in a TM. You can teach a pokemon Headbutt by talking to a guy in a pink shirt in the Illex Forest. You can Headbutt trees (Like an HM) to find certain PoKeMoN.(It vairies where you Headbutt.)
You cannot headbutt trees in any game except for Gold, Silver, Crystal, Heart Gold, and Soul Silver. You must teach a Pokemon TM 2 in GSC, or teach a Pokemon Headbutt from the Move Tutor in HGSS.
Nowhere.
Zen Headbutt is not a TM. It can be learned by leveling up, breeding, or by the Move Tutor.
In Pokemon Platinum, Flash is a TM.