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Headbutt dosn't come in a TM. You can teach a pokemon Headbutt by talking to a guy in a pink shirt in the Illex Forest. You can Headbutt trees (Like an HM) to find certain PoKeMoN.(It vairies where you Headbutt.)
u cant it not tm :(
Zen Headbutt is not a TM. It can be learned by leveling up, breeding, or by the Move Tutor.
dig
In Victory Road.