Muk is the better pokemon
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There are lots of good pokemon. Some are: Crobat, golem, steelix, victreebal, gengar,poliwrath, gyrados, hypno, alakazam, forretress( dont hate me for that one), nidoqueen and nidoking,yanmega, scizor, muk, granbull, ninetales, arcanine, etc.
get a nidoran (purple one) train it until it evolves into Nidorino, then give it a Moon Stone. You should get a Nidoking.
You find Grimer in the Fiery Path. They are rare is it may seem that they are not there but they are. Its worth the time getting Grimer then evolving it to Muk, because Muk is probably one of the stronger Poison type Pokemon that are in Emerald!
Yes. Maybe you could replace muk with one of the starters. Typhlosion would be best
Muks are rare to find in the wild, but if you are lucky you will be able to catch one in the Pokemon Mansion in Cinnabar Island. You can also catch a Grimmer instead and raise it to level 38, then it will evolve to Muk.