Muks are rare to find in the wild, but if you are lucky you will be able to catch one in the Pokemon Mansion in Cinnabar Island. You can also catch a Grimmer instead and raise it to level 38, then it will evolve to Muk.
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you can't catch muk in emerald but you can catch grimer in the fiery path and get him to level 30 and he will evolve in to muk okay
it evolves into a muk* at level 36. :)
epesode 20
A Muk Isn't A Very Special Pokemon. It Evolves From A Grimer, Which In The First Who Pokemon Games(Kanto And Johto Regions) Aren't That Hard To Find. ^.^ But, It's Hard To Find A Muk And Catch It.
You can not catch it in leafgreen,but in firered you can.