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First you need a light ball then give it to your female Pikachu afterthat you need a Pokemon in the fairy egg group like Pichu or another pikachu then breed them by going to the day care centre after they have layed their egg get it from the old man outside the day care centere and hatch it if your pichu knows volt tackle then evolve it.

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Q: How do you get Pikachu to learn volt tackle on Pokemon Platinum?
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