Electivire cannot learn Volt Tackle in Pokemon HeartGold. Only pichu, pikachu, and raichu can learn volt tackle.
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Any Pokemon that can learn a electric move
in my opinion i would use a pikachu but with a high lvl because it would learn volt tackle. but u should use whatever type of electric Pokemon you want.
there is no TM for thunderpunch but Pokemon like electivire or medicham can learn it.
I don't know all of the Pokemon that can learn Headbutt, but I know that Cubone can learn it.
No Gastly cannot learn fly in Pokémon HeartGold.