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You don't. Moltres, Zapdos and Articuno are not in this pokemon generation.
Moltres is not in ruby only firered, leafgreen and Pokemon xd gale of darkness can get moltres.
Yes, You can catch Groudon in Pokemon Emerald.
You can't catch one in Pokemon Emerald.
Moltres is a legendary pokemon all legendary pokemon are harder to capture.