No you cannot catch Entei in Pokemon Emerald.
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U CANT CATCH HIM u have to trade him or hack the game
No you cannot catch Larvitar in Pokémon Emerald.
You can't catch a sentret in Ruby version, but you can catch one in Emerald version.
no but if you catch all the hoenn pokemon you can catch jotho and kanto pokemon
The Dragonscale is an item in Pokemon Emerald version. There is a chance that certain Pokemon such a Horsea will be holding one when you catch it.