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No you cannot catch Larvitar in Pokémon Emerald.

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Q: Can you catch a Larvitar in Pokemon Emerald Version?
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No you cannot catch Entei in Pokemon Emerald.

How do you get Tyranitar in Pokemon pearl or diamond version?

Tyranitar evolves from Pupitar, which evolves from Larvitar. You can get a wild Larvitar in Diamond at Route 207. It's impossible to catch a wild Larvitar in Pearl.

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