Moltres cannot evolve or does not evolve from any Pokemon. You can catch it in Pokemon SS or HG. Hope this helps!
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No, using a Fire Stone on Pidgey will not evolve it into Moltres. Pidgey evolves into Pidgeotto which then evolves into Pidgeot. Pidgey does not have additional evolutions.
moltres
no Pokemon evolves into seviper
No you cannot find Moltres in Pokemon Black however you can get Moltres in Pokemon Black by transferring one from a previous game.
Barboach evolves into Whiscash.