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Yes, Oddish can learn sleep powder.
In the games, Oddish learns sleep powder at these levels:
Level 19 in Generation 1 (Red, Green, and Blue),
Level 18 at Generation 2 and 3 (Gold, Silver, Crystal, Ruby, Sapphire, and Emerald), and
Level 17 at Generation 4 (Diamond, Pearl, and Platinum).
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