Sleep powder is a move that can be learned by most grass type Pokemon sleep powder is not a move taught by a regular move tutor nor is it a TM you can though teach the Pokemon sleep powder if it can learn it from the super move tutor on two island.
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The move? Um... buy a TM? Or is this an item you're referring to...
sleep powder catch a butter free and level it up afew times then it will try to learn sleep powder
There are no items that can put Pokemon to sleep, only moves like hypnosis and sleep powder.
Bayleef Does Not Learn Sleep Powder in HeartGold/SoulSilver
Dark hole, hypnosis, yawn, sleep powder.