Dark hole, hypnosis, yawn, sleep powder.
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There are no items that can put Pokemon to sleep, only moves like hypnosis and sleep powder.
You can use certain moves that trap the Pokemon so that they can not Escape. (Mean look is one of them) You can also put the Pokemon to sleep or use a Master Ball on them.
Hypnosis, Yawn, Dark Void, Sing, Spore, Sleep Powder, Lovely Kiss, Grasswhistle, and metronome
Snorlax, gulpin,you name it they are all sleepy heads!
put them to sleep, or paralyze them