Butterfree learns sleep powder at level 15.
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lv. 15.
sleep powder catch a butter free and level it up afew times then it will try to learn sleep powder
Bayleef Does Not Learn Sleep Powder in HeartGold/SoulSilver
Shroomish doesn't learn Sleep Powder.
Yes, Oddish can learn sleep powder. In the games, Oddish learns sleep powder at these levels: Level 19 in Generation 1 (Red, Green, and Blue), Level 18 at Generation 2 and 3 (Gold, Silver, Crystal, Ruby, Sapphire, and Emerald), and Level 17 at Generation 4 (Diamond, Pearl, and Platinum).