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Venusaur learns Sleep Powder at level 15, but assuming you are using a legit, evolved Venusaur, you can do one of these two.
1. Train an Ivysaur to learn Sleep Powder at level 15
2. Have the move tutor teach it to your Venusaur (I don't think move tutors exist in Pokemon Red/Blue/Yellow)
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What level does Bulbasaur learn sleep powder?
Bulbasaur learns it at level 41. (Ivysaur learns it at 46 and Venusaur learns it at 55)
What moves does Venusaur learn in Pokemon Yellow?
Venusaur Learns:- Growth Lv.43 Sleep Powder Lv.55 Solar Beam Lv.65
What level does Bayleef learn Sleep Powder at in Pokemon HeartGold and SoulSilver?
Bayleef Does Not Learn Sleep Powder in HeartGold/SoulSilver
What level does butter free learn sleep powder in fire red?
Butterfree learns sleep powder at level 15.
Does shroomish learn sleep powder?
Shroomish doesn't learn Sleep Powder.
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