In which book? In book 1 and 2 she is their supervisor.
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Because her "job" is an escort, which means that it's his or her main duty to accompany any tributes and/or victors of which district he or she "works for."
Katniss Was Passed Out And Peeta was still in the arena
She doesn't get to see Peeta because Peeta wants to kill her. Peeta was kidnapped by the Capitol and they used trackerjacker venom to corrupt the images of Katniss in Peeta's head so that when he sees her, he will try to kill her.
First there a pretend couple, then they're just friends (while their still a pretend couple), then Katniss finds out she really DOES love Peeta, then in the end of the last book Mockinjay, she marries him.
Peeta is captured by the capital, so that they can use him Katniss. They torture Peeta, and make him try to convince Katniss that a war is not a good idea, and that President Snow should still lead. The capital will go to any lengths of torturing Peeta, to break Katniss, and end the rebellion. Poor Peeta :(
When Peeta was swinging a knife around cutting down plants, he accidentally hit a force field that shocked him so bad that his heart stopped. Finnick performed CPR on Peeta which saved his life. He could have just left Peeta to die, but he didn't.