The volturi want to fight the Cullen family because of renesmee ( daughter of Bella and edward ) also because Bella is not a vampire and she knows to much about vampires. hope this helps x
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The Volturi are out to kill Bella and the Cullens as they are protecting Renesmee in Breaking Dawn as the think that Renesmee is an Immortal child.
Bree broke the rules and carlisle offered for her to become a Cullen but the volturi did not allow it so Jane told Felix to kill her
Edward went to Italy because he thought Bella was dead and he couldn't live without her.He also wanted to die; the thought of life without Bella was unbearable, so he went to the Volturi to ask them to kill him.
I think he meant that they knew that even if theydidn't kill him ( or whatever it is you'd like to call it ) they would end up doing it in the end. Which explains the whole 'step into the sunlight so that the Volturi kill me' thing. :]
Resnesmee is Bella's daughter. Just like any other mother, if her child was in trouble, she would want to save their child because she loes her daughter and so does Edward.
Marcus, Caius and Aro everyone else considered part of the Volturi- besides the wives- are part of the Volturi Guard.