Marcus, Caius and Aro everyone else considered part of the Volturi- besides the wives- are part of the Volturi Guard.
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The volturi do not get an invite to their wedding however one of Edwards cousins goes to the volturi and tells them they have had a baby and the volturi want this baby -hope this helped
The shots of the town were in Italy, but the scenes with the Volturi were shot in Portland, Wa.
Volterra, Italy.. which is in Rome by the way :D as you can tell.. i am a giantt Volturi fan xD
Bree broke the rules and carlisle offered for her to become a Cullen but the volturi did not allow it so Jane told Felix to kill her
Stephenie Meyer has not given enough information about Caius (or any other Volturi member, for that matter) for this question to be answered. No one really knows how he did become apart of the Volturi, though it would be interesting to find out.