you need to raise your blastoise's friendship to MAX. to do this you can: LV.UP give it vitamins such as: hp up, carbos,zinc,calcium,or protein. you can get your pokemon massaged by daisy ( gary/blues sister) until the lady lets you. It works!
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he learns hydro pump at in leve 50 something, and a lady in two island teaches him hydro cannon
teach your starter Pokemon its ultimate move but needs to be a high level. venasaur=frenzy plant charizard=blast burn blastoise=hydro canon
a blastoise because she teaches it hydro pump which is the best move ever!!
I think the best team on Pokemon fire red is...Mewtwo- Focus punch, Solarbeam, Earthquake and physic.Blastoise- Waterfall, Surf, Hydro pump and Hydro cannon (get hydro cannon from the lady's house in island two up the water fall.)Raikou / Nidoking (I have not got Raikou yet but when i get it i will tell you the moves.)Cut, Strength, Sludge bomb and Megahorn.Zapdos- Shock wave, Thunder, Drill peck and Aerial ace.Moltres- Sky attack, Overheat, Fire blast and Flamethrower.Articuno- Blizzard, Fly, Sheer cold and Ice beam.Hope it helped. Obviously they all have to be the highest level you can be bothered to get them to!I will update when i get Raikou!
Mew's SpecialtyMew, an extraordinary Pokemon, can virtually learn all moves no matter what. However, if you try in the Pokemon games, Mew can't possibly learn special moves like Blast Burn, Frenzy Plant, Hydro Cannon, Volt Tackle, Heart Swap, Judgement, etc. In FireRed and LeafGreen, the lady at Cape Brink only teaches elemental Hyper Beams to Venasaur, Blastoise, and Charizard. In the games, Mew can only learn the moves that it learns by leveling up, from Move Tutors, and all the TMs and HMs that you have.