the game corner exchange in celadon city.
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It can learn Thunderbolt through TM.
You could get it at Celadon City in the game corner for 4,000 coins.
- Thundershock - Tailwhip - Quick Attack - Thunderbolt
I think you are able to buy the TM for this at celdon city games corner for around £4,000 ?
you dont find it but if you have a pikachu it learn thunderbolt(tm 24)at lv 26 or you can buy it at the celadon game corner