It can learn Thunderbolt through TM.
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- Thundershock - Tailwhip - Quick Attack - Thunderbolt
Yes, it learns Thunderbolt at level 26.
It will learn "Thunder" (with an attack of 120 and accuracy rate of 70), a far better move than "Thunderbolt", at level 61. But it does not learn "Thunderbolt". You can, though, give it a "Thunderbolt" TM =)
A Pokemon has to learn it as it levels up
Pokemon!!!!!!!!