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In Pokemon FireRed you can't, but in Pokemon leafgreen you can get it then trade it to Pokemon firered.
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Earn +20 ptsQ: Where to get staryu in firered?
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Can catch a staryu in Pokemon firered?
NO you cant but you can in leafgeen
Where do you find staryu on pokemon firered?
Super Rod in "Canalave City"
How do you catch staryu on Pokemon FireRed?
use good rod on route 19
What Pokemon evolve with a water stone in Pokemon FireRed?
Poliwhirl → Poliwrath, Shellder → Cloyster, Staryu → Starmie and Eevee → Vaporeon
What Pokemon can you evolve with a waterstone in Pokemon ruby?
lombrea, evee, poliwhirl, shellder, and staryu. some of these can only be found in firered and leafgreen so you will need to trade. that's all I can think of.
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