You get the EXP. share from the president of something in Rustboro City when you are going to deliver a message to Steven and someone else.
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Well, you give it to a Pokemon in your party. Then when any other Pokemon in your team defeats an opponents Pokemon, the Pokemon with exp share gets part of the experience points you get for defeating the opponents Pokemon. e.g. You give the exp share to charmander your Blastoise defeats a Zubat. You get 500 exp total, whcih is divided between charmander and Blastoise.
The best way is challenge the elite four with your Pokemon or a Pokemon holding exp. share. The better is to use gameshark codes for rare candies.
give the exp share to a weak Pokemon when you use any Pokemon to fight exp goes to the fighting Pokemon and the 1 with the exp share.
to obtain 5,ooo exp in Pokemon leaf green is to put a expirance share on the Pokemon you are training (best place to train is Pokemon league or victory road or clearun cave)
Its a item that you give to a Pokemon and it gives the Pokemon that you gave the exp share to exp points to help a Pokemon gain levels