TM24 (Thunderbolt) is located in the P2 Laboratory.
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It can learn Thunderbolt through TM.
You can't get an HTM for thunderbolt if that's what you mean. Usually pokemon come with the skill thunderbolt like an ampharos, my ampharos learned discharge, thunderbolt, thunderpunch, and recharge. Also a large amount of electric pokemon come with this move or earn this move from evolving.
Yes, it learns Thunderbolt at level 26.
you can buy the TM thunderbolt in the rocket price shop in celadon city