You can't get an HTM for thunderbolt if that's what you mean. Usually pokemon come with the skill thunderbolt like an ampharos, my ampharos learned discharge, thunderbolt, thunderpunch, and recharge. Also a large amount of electric pokemon come with this move or earn this move from evolving.
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In Goldenrod city Game Corner, you can get Thunderbolt for 10,000 coins, or go to Cerulean Cave.
Goldenrod game corner OR Cerulean cave in which u can only get by beating the elite 4 of kanto
There is no best Pokemon on Pokemon HeartGold.
there is no Pokemon Mansion in Heartgold.
TM24 (Thunderbolt) is located in the P2 Laboratory.