hearthome city, next to the mart, i think
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No. To obtain poffins you have to make them yourself in Hearthome City in the Poffin House.
Instead of Pokeblocks, Platinum, Diamond, and Pearl use Poffin. They use the same flavors like Dry is Beauty, Bitter is Smart, etc. You can make them in the Poffin house in Hearthome City.
Pokeblock's are not in diamond instead there called poffin's, just like ruby, sapphire and emerald in the Pokemon contests you can create your own poffin using berries.
The Poffin maker's house, it is left from the Pokemart in Hearthome City and ask the lady in front of the Poffin Maker. If you need a poffin case go to the Pokemon Fan Club and talk to the old man at the couch.
yes because they'll go straight to your poffin case and lose their effect just to raise your pokemons stats.