No. To obtain poffins you have to make them yourself in Hearthome City in the Poffin House.
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You can't!
If you meen Poffins then its at Hearthome City
they wont eat anymore poffins that's all sorry
you can't but you can make poffins Poffins in diamond and pearl replace what used to be pokeblock.
You can't buy them you have to make your own.