Behind the Valley Windworks. Surf right from the bridge connecting to Route 205, and go all the way up behind the Valley Windworks to a little patch of ground. Item ball there is TM Thunderbolt.
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kil a pichachu then go to battl frontier and get lots of battle points then buy the TM thunderbolt
Behind the Valley windworks. The Valley windworks is next to floamara town.
TM24 (Thunderbolt) is located in the P2 Laboratory.
It can learn Thunderbolt through TM.
You can't get an HTM for thunderbolt if that's what you mean. Usually pokemon come with the skill thunderbolt like an ampharos, my ampharos learned discharge, thunderbolt, thunderpunch, and recharge. Also a large amount of electric pokemon come with this move or earn this move from evolving.