Starmie cannot be found in the wild in Fire Red. To get Starmie, get the Super Rod from the Fishing Guru in the house between Lavender Town and Fuschia City. Then, go to Vermillion City and fish in the ocean, and you should eventually land a Staryu. Catch it, then buy a Water Stone from the Department Store in Celadon City. Use the Water Stone on Staryu, and it will evolve into Starmie.
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no you cannot find starmie in fire red you can trade starmie from Pokemon leaf green
u dont get a starmi in fired u have to trade.
Poliwhirl → Poliwrath, Shellder → Cloyster, Staryu → Starmie and Eevee → Vaporeon
You cant find it in Firered only leafgreen.
While it was possible to find missingno. in Red version, it is not possible to find it in FireRed.