you can check the pokedex, it is in fiery path.... and many caves! Just check the pokedex, it's quicker.
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You may capture a Machop in Fiery Path or Jagged Pass in Pokemon Emerald.
Not really. All you have to do is catch a machop and evolve it.
raikou cannot be caught on Pokemon ruby
No.
You can't catch a sentret in Ruby version, but you can catch one in Emerald version.